ChemInform Abstract: Sulfur Dichloride—Hexamethylphosphoric Triamide Complex — A Reagent for Imination of Geminal Dichlorides.
✍ Scribed by I. V. Bodrikov; I. Yu. Shebelova; N. V. Nikitina
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 20 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
Enolates with Imines. -Based on a ternary complex reagent, which comprises three components, a chiral ether ligand, an achiral lithium amide and (I), the asymmetric addition of (I) to an imine (II) leads to the β-lactams such as (III) and (V) in high enantiomeric excess. The enantioselectivity and