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ChemInform Abstract: Sulfoxides in Radical Chemistry. High 1,2-Asymmetric Induction in Radical Cyclizations.

โœ Scribed by Christoph Imboden; Thierry Bourquard; Olivier Corminboeuf; Philippe Renaud; Kurt Schenk; Mohamed Zahouily

Book ID
101877929
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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Sulfoxides in radical chemistry. High 1,
Sulfoxides in radical chemistry. High 1,2-asymmetric induction in radical cyclizations
โœ Christoph Imboden; Thierry Bourquard; Olivier Corminboeuf; Philippe Renaud; Kurt ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 257 KB

Very high levels of 1,2-asymmetric induction (>50:1) from the sulfur chiral center are reached for the cyclization of substituted l-(ortho-chlorophenyl)sulfinyl-5-hexen-1-yl radicals. These reactions represent the first cases of high asymmetric 1,2-induction during cyclizations of non-stabilized sul