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ChemInform Abstract: Substituted 2,3-Dihydroisoxazoles (δ4-Isoxazolines) via Palladium-Mediated Cyclization of Propargylic N-Hydroxyureas.

✍ Scribed by E. J. STONER; B. A. RODEN; S. CHEMBURKAR

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Substituted 2,3-Dihydroisoxazoles (δ4-Isoxazolines) via Palladium-Mediated Cyclization of Propargylic N-Hydroxyureas. -During the investigation of substituted hydroxylamine derivatives such as (I) as inhibitors of the enzyme 5-lipoxygenase, 2,3-dihydroisoazoles (II) are detected as byproducts. An improved Pd(II)-catalyzed synthesis allows the preparation of (II) from (I) in good yields. -(STONER, E.

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