Five-coordinate bicycloazastannoxides containing a b-hydroxy-␣-amino acid moiety were synthesized. By hydrolysis under the action of 10% HCl, five b-hydroxy-␣-amino acids were prepared, and their structures were characterized by 1 H NMR spectroscopy, MS, and elemental analyses. The mechanism of the
✦ LIBER ✦
ChemInform Abstract: Study on Reactivity of Five-Coordinate Bicycloazastannoxides. Part 3. New Method for Preparing β-Hydroxy-α-amino Acids.
✍ Scribed by Xiao Ping Yang; San Wei Wang; Wen Sheng Guo; Ji Tao Wang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
1999 hydroxycarboxylic acids hydroxycarboxylic acids (ether carboxylic acids) and esters (benzene compounds) Q 0450 30 -099 Study on Reactivity of Five-Coordinate Bicycloazastannoxides. Part 3. New Method for Preparing β-Hydroxy-α-amino Acids.
-A series of β-hydroxy-α-amino acids (IV) is prepared by condensation of the organotin complex (I) with aldehydes and subsequent hydrolysis of the so formed five-coordinate bicycloazastannoxides containing the β-hydroxy-α-amino acid moiety (III). -(YANG,
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⚖ 136 KB