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ChemInform Abstract: Study on Reactivity of Five-Coordinate Bicycloazastannoxides. Part 3. New Method for Preparing β-Hydroxy-α-amino Acids.

✍ Scribed by Xiao Ping Yang; San Wei Wang; Wen Sheng Guo; Ji Tao Wang


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


1999 hydroxycarboxylic acids hydroxycarboxylic acids (ether carboxylic acids) and esters (benzene compounds) Q 0450 30 -099 Study on Reactivity of Five-Coordinate Bicycloazastannoxides. Part 3. New Method for Preparing β-Hydroxy-α-amino Acids.

-A series of β-hydroxy-α-amino acids (IV) is prepared by condensation of the organotin complex (I) with aldehydes and subsequent hydrolysis of the so formed five-coordinate bicycloazastannoxides containing the β-hydroxy-α-amino acid moiety (III). -(YANG,


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Study on reactivity of five-coordinate b
✍ Yang Xiao Ping; Wang San Wei; Guo Wen Sheng; Wang Ji Tao 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB

Five-coordinate bicycloazastannoxides containing a b-hydroxy-␣-amino acid moiety were synthesized. By hydrolysis under the action of 10% HCl, five b-hydroxy-␣-amino acids were prepared, and their structures were characterized by 1 H NMR spectroscopy, MS, and elemental analyses. The mechanism of the