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ChemInform Abstract: Studies Towards the Total Synthesis of (-)-Caulerpenynol, a Toxic Sesquiterpenoid of the Green Seaweed Caulerpa taxifolia.

✍ Scribed by Laurent Commeiras; Jerome Thibonnet; Jean-Luc Parrain

Book ID
102040588
Publisher
John Wiley and Sons
Year
2009
Weight
18 KB
Volume
40
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Studies towards the Total Synthesis of (
Studies towards the Total Synthesis of (–)-Caulerpenynol, a Toxic Sesquiterpenoid of the Green Seaweed Caulerpa taxifolia
✍ Laurent Commeiras; JΓ©rΓ΄me Thibonnet; Jean-Luc Parrain πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 283 KB

## Abstract The first diastereoselective synthesis of the antimicrobial and cytotoxic agent (–)‐caulerpenynol (**2**) was achieved in relatively few steps from commercially available (__S__)‐malic acid. Highlights of this synthesis include the nonracemization of the sensitive α‐hydroxy ketone moiet

Caulerpenyne-Amine Reacting System as a
Caulerpenyne-Amine Reacting System as a Model for in vivo Interactions of Ecotoxicologically Relevant Sesquiterpenoids of the mediterranean-adapted tropical green seaweed caulerpa taxifolia
✍ Antonio Guerriero; Daniela Depentori; Michele D'Ambrosio; Francesco Pietra πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 German βš– 525 KB

## Abstract Caulerpenyne (1), the most abundant of the ecotoxicologically relevant sesquiterpenoids of the Mediterranean‐adapted tropical green seaweed __Caulerpa taxifolia__, was found to react with Et~3~N or pyridine in MeOH by initial deprotection of C(1)HO to give oxytoxin 1 (2a), previously is