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ChemInform Abstract: Studies on α-Sialylation Using Sialyl Donors with an Auxiliary 3- Thiophenyl Group.

✍ Scribed by V. MARTICHONOK; G. M. WHITESIDES

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199749234

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✦ Synopsis

Studies on α-Sialylation Using Sialyl Donors with an Auxiliary 3-Thiophenyl Group.

-Sialylation of α-lactoside (II) with (I) affords the α-sialoside (III) in good yield and with excellent stereoselectivity. A possible mechanism of sialylation with (I) that involves intermediate . alpha.-and β-nitrilium ions is discussed. -(MARTICHONOK, V.; WHITESIDES, G.

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