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ChemInform Abstract: Studies on 1,3-Allylic Strain Control on Dihydroxylations and Hydrogenations of α-Substituted Enoates.

✍ Scribed by P. M. KAUPPINEN; A. M. P. KOSKINEN

Book ID
101848714
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Studies on 1,3-Allylic Strain Control on Dihydroxylations and Hydrogenations of α-Substituted Enoates
✍ Pasi M Kauppinen; Ari M.P Koskinen* 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 440 KB

L-serinederivedenoates8 and9 were subjectedto catalytic. dihydroxylationand hydrogenation reactions.The observedselectivitiescan be explainedto arisefrom 1,3-allylicstrain. @ 1997Elsevier ScienceLtd. In conjunction with our efforts to asymmetric synthesis of Lincomycin type antibiotics, we needed a