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ChemInform Abstract: Structures of arachno- and hypho-B10 Clusters and Stability of Their Possible Lewis Base Adducts ([B10H12]2-, [B10H12×L]2-, [B10H12×2L]2-, [B10H13]-, [B10H13×L]-, [B10H12×2L]). An ab initio/IGLO/NMR Investigation.

✍ Scribed by M. HOFMANN; P. VON RAGUE SCHLEYER

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199901001

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✦ Synopsis

Structures of arachno-and hypho-B 10 Clusters and Stability of Their Possible Lewis Base Adducts ([B 10 H 12

). An ab initio/IGLO/NMR Investigation.

-Ab initio/IGLO/NMR studies indicate that [B 10 H 12 ] 2-favors a C 2 symmetric structure in solution which can be derived from B 10 H 14 by removing two bridging protons. Earlier postulated complex formation with solvent molecules is not confirmed. -(HOFMANN,

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