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ChemInform Abstract: Structures and Physical Properties of Rare-Earth Zinc Antimonides Pr6Zn1+xSb14+y and RE6Zn1+xSb14 (RE: Sm, Gd—Ho).

✍ Scribed by Yi Liu; Ling Chen; Long-Hua Li; Li-Ming Wu


Publisher
John Wiley and Sons
Year
2009
Weight
18 KB
Volume
40
Category
Article
ISSN
0931-7597

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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 °C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4•H2O. The isostructural compounds crystallize in the m