Intramolecular 1,2-H shifts of alkyl or alkylchlorocarbenes are often very rapid making it difficult to relate structure with reactivity in terms of absolute rate constants. For example, k H in hydrocarbon solvents at 25 °C for Me2CHCCI, PhCH(Me)CC1, or EtCC1 exceeds l0 s s-~, 1' 2 while k, for PhCH
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ChemInform Abstract: Structure—Reactivity Dependence in the Rearrangements of a Family of Alkylacetoxycarbenes (I).
✍ Scribed by R. A. MOSS; D. C. MERRER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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