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ChemInform Abstract: Structure, Molecular Motion, and Phase Transition of a Highly Disordered Crystal [Co(NH3)6](ClO4)3.

✍ Scribed by Natalia Gorska; Akira Inaba; Yasukazu Hirao; Edward Mikuli; Krystyna Holderna-Natkaniec

Book ID: 112048777
Publisher: John Wiley and Sons
Year: 2012
Weight: 20 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201233003

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## Crystal Structure of Indium Perchlorates [In(H -X-ray studies indicate that [In(H 2 O) 6 ](ClO 4 ) 3 crystallizes in the cubic system (space group I43m, Z = 32), whilst the corresponding trihydrate possesses a rhombohedral structure (space group R3c, Z = 2). -(ILYUKHIN, A.

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ChemInform Abstract: The Crystal Structures of the Cyano Complexes [Co(NH3)6][Fe(CN)6], [Co(NH3)6]2 [Ni(CN)4]3×2H2O, and [Cu(en)2][Ni(CN)4].

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ChemInform Abstract: A Rational Synthesis of New Anion [HgBr4Cl]3-: Synthesis, Characterization and Single Crystal X-Ray Structure Determination of [Co(NH3)6][HgBr4Cl].

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## Abstract Single crystals of the title compound are obtained from an hot aqueous solution of [Co(NH~3~)~6~]Cl~3~, HgBr~2~, and KBr (75% yield).

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## Abstract Red large single crystals of the new title compound are prepared from an aqueous solution of H~3~BO~3~, CoCl~2~, and NH~4~OH (pH 9, 25 °C, 3 d).