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ChemInform Abstract: Structure Based Interference with Insect Behavior - Cyclopropene Analogues of Pheromones Containing Z-Alkenes.

✍ Scribed by J. R. AL DULAYYMI; M. S. BAIRD; M. J. SIMPSON; S. NYMAN; G. R. PORT


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Structure Based Interference with Insect Behavior -Cyclopropene Analogues of Pheromones Containing Z-Alkenes.

-Analogues of pheromones of three insect species (cf. (VIa), (VIII), and (IX), resp.) in which a Z-alkene is replaced by a cyclopropene moiety are synthesized via a phasetransfer catalyzed addition of dibromocarbene to 2-bromoalkenes as the key reaction. These cyclopropene analogues interfere with normal mating behavior for each species. -(AL DULAYYMI,