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ChemInform Abstract: Structure and Reactivity of a Preactivated sp2—sp3 Diboron Reagent: Catalytic Regioselective Boration of α,β-Unsaturated Conjugated Compounds.

✍ Scribed by Ming Gao; Steven B. Thorpe; Christian Kleeberg; Carla Slebodnick; Todd B. Marder; Webster L. Santos

Publisher: John Wiley and Sons
Year: 2011
Weight: 35 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201133182

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✦ Synopsis

Abstract

The diborane (II) is an efficient reagent for the Cu‐catalyzed β‐boration of various α,β‐unsaturated ketones, aldehydes, esters, amides, and nitriles to produce synthetically important organo‐boron compounds.

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