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ChemInform Abstract: Structure and Conformational Studies of the Disaccharides Derived from the Inner Core of the Lipopolysaccharide Isolated from Sinorhizobium freddii SMH12.

✍ Scribed by Francisco J. Fernandez de Cordoba; Miguel A. Rodriguez-Carvajal; Pilar Tejero-Mateo; Antonio M. Gil-Serrano

Publisher
John Wiley and Sons
Year
2009
Weight
15 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract The conformational and dynamic behavior of the O‐antigen of the lipopolysaccharide of __Sinorhizobium fredii__ SMH12, a wide‐range host bacterium isolated from nodulated soybean plants growing in Vietnam, was studied. The O‐antigenhas a repeating unit consisting of the trisaccharide →4)

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The title compound (PE-Kdo) was isolated after hydrolysis of the lipopolysaccharides of Escherichia coli K-12 strain W3100 and Salmonella minnesota strains R4 and R7, and the location of the 2-aminoethyl phosphate group at position 7 was established by 13C-n.m.r. spectroscopy. Derivatives of PE-Kdo