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ChemInform Abstract: Structure and Conformational Properties of Azido(difluoro)phosphane, F2PN3.

โœ Scribed by Xiaoqing Zeng; Helmut Beckers; Helge Willner; Raphael J. F. Berger; Stuart A. Hayes; Norbert W. Mitzel

Publisher
John Wiley and Sons
Year
2011
Weight
19 KB
Volume
42
Category
Article
ISSN
0931-7597

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Structure and Conformational Properties
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Azido(difluoro)phosphane, F 2 PN 3 , is a colorless gas, which freezes to a glassy solid at ca. -120 ยฐC, and the boiling point obtained by extrapolating the vapor-pressure curve is 8 ยฐC. It has been characterized by IR (gas phase, Ar matrix), Raman (liquid, amorphous, and crystalline solid), and 19

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## Abstract The title compounds are prepared by solid state reactions using SrPn (Pn: As, Sb), SrF~2~, Sm~2~O~3~, TiO~2~, and Ti as starting materials (1000โ€”1150 ยฐC, 50 h) and characterized by powder XRD, resistivity, susceptibility, Hall coefficient, thermoelectric power, and heat capacity measure