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ChemInform Abstract: Structural and Thermal Gas Desorption Properties of Metal Aluminum Amides.

✍ Scribed by Taisuke Ono; Keiji Shimoda; Masami Tsubota; Satoshi Hino; Ken-ichi Kojima; Takayuki Ichikawa; Yoshitsugu Kojima


Publisher
John Wiley and Sons
Year
2010
Weight
19 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The compounds M[Al(NH~2~)~4~]~x~ (M: K, Mg, Ca; x = 1, 2) along with previously reported LiAl(NH~2~)~4~ and NaAl(NH~2~)~4~ are prepared by ball milling under liquid NH~3~ and their structural and gas desorption properties are characterized by synchrotron powder XRD, FTIR and NMR spectroscopy, and thermogravimetry coupled with mass spectroscopy.


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