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ChemInform Abstract: Straightforward Synthesis of Enantiomerically Pure (3S,4R)- and (3R,4S)-3,4-Isopropylidenedioxypyrroline 1-Oxide, Precursors of Functionalized cis-Dihydroxy Azaheterocycles, by a Novel “One-Pot” Procedure.

✍ Scribed by Stefano Cicchi; Massimo Corsi; Alberto Brandi; Andrea Goti


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantiomerically Pu
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Enantiomerically Pure 3-Substituted 2-Phenylprolines by Caesium Fluoride/Tetramethoxysilane Mediated 1,4-Addition of (3S,5R)-Diphenylmorpholin-2-one to Acrylates. -In continuation of the asymmetric synthesis of nonproteinogenic amino acids, the silane-mediated 1,4-addition of acrylates (II) to the