𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Stereospecificity in the Au-Catalyzed Cyclization of Monoallylic Diols. Synthesis of (+)-Isoaltholactone.

✍ Scribed by William P. Unsworth; Kiri Stevens; Scott G. Lamont; Jeremy Robertson

Publisher
John Wiley and Sons
Year
2011
Weight
27 KB
Volume
42
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A concise synthesis of the title compound (V) is presented with the Au‐catalyzed cyclization as key step.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Chirality Transfer
ChemInform Abstract: Chirality Transfer in Au-Catalyzed Cyclization Reactions of Monoallylic Diols: Selective Access to Specific Enantiomers Based on Olefin Geometry.
✍ Aaron Aponick; Berenger Biannic πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 49 KB

## Abstract Treatment of either geometrical isomer of a chiral alcohol substrate under conditions A) affords the enantiomeric heterocyclic ring products with a high level of chirality transfer at the new asymmetric center.