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ChemInform Abstract: Stereospecific Synthesis of (-)-allo-Muscarine from D-Glucose: Novel Routes to the Key Chiral Synthon.

✍ Scribed by V. POPSAVIN; O. BERIC; M. POPSAVIN; J. CSANADI; S. LAJSIC; D. MILJKOVIC

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Stereospecific Synthesis of (-)-allo-Muscarine from D-Glucose: Novel Routes to the Key Chiral Synthon.

-A simple and convenient four-step conversion of L-idose (I), which is readily available from D-glucose, to key intermediate (VI) in the (-)-allo-muscarine (VII) synthesis is described. Compared to former syntheses, the overall yield of (VI) is significantly improved. The new route represents an efficient formal total synthesis of (VII) from D-glucose. -(

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