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ChemInform Abstract: Stereospecific Ring-Opening Reaction of Epoxy Sulfides with Phenylboronic Acid via Episulfonium Ions.

โœ Scribed by Hiroyuki Hayakawa; Naoko Okada; Masaaki Miyashita


Book ID
101882128
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Stereospecific ring-opening reaction of
โœ Hiroyuki Hayakawa; Naoko Okada; Masaaki Miyashita ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

The ring-opening reaction of epoxy sulfides with phenylboronic acid in benzene has been demonstrated to occur stereospecifically via episulfonium ions, i.e., with double inversion of configuration, giving rise to phenylboronic esters of 2,3-diols in quantitative yields.