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ChemInform Abstract: Stereospecific Preparation of Glycidic Esters from 2-Chloro-3- hydroxyesters. Application to the Synthesis of (2R,3S)-3- Phenylisoserine.

โœ Scribed by O. CABON; D. BUISSON; M. LARCHEVEQUE; R. AZERAD


Book ID
112027367
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Nucleophilic Additi
โœ P. MERINO; E. CASTILLO; S. FRANCO; F. L. MERCHAN; T. TEJERO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 38 KB ๐Ÿ‘ 2 views

Nucleophilic Additions of Grignard Reagents to N-Benzyl-2,3-O-isopropylidene-D-glyceraldehyde Nitrone (BIGN). Synthesis of (2S,3R) and (2S,3S)-3-Phenylisoserine. -The addition of Grignard reagents to the nitrone (I) proceeds with high anti or syn selectivity depending on the Lewis acid used. The re