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ChemInform Abstract: Stereospecific Polymerization of 1,3-Diene Monomers in the Crystalline State

✍ Scribed by Akikazu Matsumoto

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Anionic Polymerization of Cyclohexa-1,3-
Anionic Polymerization of Cyclohexa-1,3-diene in Cyclohexane with High Stereoregularity and the Formation of Crystalline Poly(cyclohexa-1,3-diene)
✍ Roderic P. Quirk; Fengxiang You; Lei Zhu; Stephen Z. D. Cheng πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 120 KB

## Abstract Polymerization of cyclohexa‐1,3‐diene using __sec__‐BuLi as initiator in cyclohexane produces both soluble (70–90 wt.‐%) and insoluble (10–30 wt.‐%) fractions depending on the temperature. The insoluble poly(cyclohexa‐1,3‐diene) was crystalline as determined by X‐ray diffraction and dif

Chain Conformations in the Crystalline F
Chain Conformations in the Crystalline Field of Syndiotactic Vinyl Polymers Deriving from 1,3-Diene Monomers. Analysis by Molecular Mechanics
✍ Beniamino Pirozzi; Roberto Napolitano; Simona Esposito πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 147 KB

## Abstract **Summary:** Conformational energy calculations on the chain conformation in the crystalline field have been performed for various syndiotactic vinyl polymers deriving from 1,3‐diene monomers. Energy maps as a function of the independent torsion angles have evidenced for all the polymer