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ChemInform Abstract: Stereospecific Access to Trisubstituted Enol Ethers from Vinylsilanes.

✍ Scribed by J. BARLUENGA; L. J. ALVAREZ-GARCIA; G. P. ROMANELLI; J. M. GONZALEZ

Book ID
101857291
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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Stereospecific Access to Trisubstituted
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The reactionof RCH=CHSiMe3(R: alkyl or aryl) with IPy2BFJHBF4and a set of representative alcohols affords the comespondingaddition products as a single regio-@ stereoisomersin good yield. Subsequentdehydroicdination with DBU furnishes silyl-substituted enol ethers. @ 1997Elsevier Science Ltd.

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