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ChemInform Abstract: Stereoselective Total Synthesis of (.+-.)-Thielocin Alβ.

✍ Scribed by Yves Genisson; Peter C. Tyler; R. G. Ball; Robert N. Young


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Tot
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ChemInform Abstract: Stereoselective Syn
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Stereoselective Synthesis of β-Hydroxycyclohexanones. -A stereoselective route to β-hydroxycyclohexanones is reported. Thus Takai alkylidenation of the aldol (I) followed by desilylation and a novel anionic oxy-Cope rearrangement provides an enolate which undergoes 6-(enolendo)-exo-trig cyclization