ChemInform Abstract: Stereoselective Synthesis of trans-2-Ethynyl-3-hydroxytetrahydropyran Derivatives.
β Scribed by E. ALVAREZ; R. PEREZ; M. RICO; R. M. RODRIGUEZ; M. C. SUAREZ; J. D. MARTIN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Stereoselective Synthesis of Methyl trans-Chrysanthemate and Related Derivatives. -The title esters (III) and (IV) are prepared by a novel type of cyclopropane formation. It is noteworthy that the earlier reported thionyl chloride-triethylamine method for the cyclization step is not successful. In