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ChemInform Abstract: Stereoselective Synthesis of the Functionalized C2—C10 Fragment of Clavulactone.

✍ Scribed by Zuozhong Zhou; Dong Suo; Zhenyu Yang; Lin Chen; Taishan Hu; Zhujun Yao

Publisher
John Wiley and Sons
Year
2009
Weight
33 KB
Volume
40
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of the Functionalized C2–C10 Fragment of Clavulactone
✍ Zuozhong ZHOU; Dong SUO; Zhenyu YANG; Lin CHEN; Taishan HU; Zhujun YAO 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 110 KB

A stereoselective synthesis of all functionalized C2-C10 fragment 13 of the antitumor marine natural product clavulactone was accomplished, starting from the commercially available 3-methylglutaric acid anhydride. Desymmetrization of 3-methylglutaric acid anhydride with (S)-α-phenylethanamine was su