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ChemInform Abstract: Stereoselective Synthesis of the C3—C17 Bis-oxane Domain of Phorboxazole A.

✍ Scribed by R. D. CINK; C. J. FORSYTH

Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Convergent Synthesi
ChemInform Abstract: Convergent Synthesis of the C31-C46 Domain of the Phorboxazole Natural Products.
✍ F. AHMED; C. J. FORSYTH 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

Convergent Synthesis of the C31-C46 Domain of the Phorboxazole Natural Products. -The synthetic fragment (V) representing the C31-C46 domain of the phorboxazole natural products is prepared in 15 steps. Key-step is the CrCl 2 /NiCl 2 mediated coupling of the aldehyde (I) with the dienyl iodide (II)