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ChemInform Abstract: Stereoselective Synthesis of the Bicyclic Core Structure of the Highly Oxidized Sesquiterpene Neoliacinic Acid.

✍ Scribed by J. S. CLARK; A. G. DOSSETTER; W. G. WHITTINGHAM


Book ID
112039571
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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A bicyclo[6.2.1]undecane structure, a model for the core structure of several biologically active furanoheliangolide sesquiterpenes, was synthesized through a retroΒ±aldol reaction from a tricyclo-[6.2.1.0 2,7 ]undecane. The required tricyclic compound was prepared by a DielsΒ±Alder reaction followed