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ChemInform Abstract: Stereoselective Synthesis of Tetrahydrofurans and Linear Methyl Enol-Ethers from Glycals.

✍ Scribed by E. BETTELLI; P. D'ANDREA; S. MASCANZONI; P. PASSACANTILLI; G. PIANCATELLI

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Stereoselective Synthesis of Tetrahydrofurans and Linear Methyl Enol-Ethers from Glycals.

-A general method is reported, which leads either to a ring-contraction or to ring-opening compounds with complete stereoselectivity. The flexibility and the utility of the method are shown by the TTN-promoted ring-transformations of cyclic enol-ethers such as aucubin (XI).

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