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ChemInform Abstract: Stereoselective Synthesis of Enantiopure Amino Compounds, via Mitsunobu Azidation of (2S,Rs)-1-(p-Tolylsulfinyl)butan-2-ol.

✍ Scribed by Pierfrancesco Bravo; Giancarlo Cavicchio; Marcello Crucianelli; Andrea Poggiali; Alessandro Volonterio; Matteo Zanda

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199915092

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✦ Synopsis

Stereoselective Synthesis of Enantiopure Amino Compounds, via Mitsunobu Azidation of (2S,Rs)-1-(p-Tolylsulfinyl)butan-2-ol.

-Starting with the azidation of the chiral β-sulfinyl alcohol (I), a highly stereoselective synthesis of the enantiopure amide (VII) is reported. -(BRAVO,

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