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ChemInform Abstract: Stereoselective Synthesis of (E)-Chloroenynes or (E,E)-Chlorodienes Starting from a Stereoisomeric Mixture of 1,2-Dichloroethylenes.

✍ Scribed by Mouad Alami; Jean-Francois Peyrat; Jean-Daniel Brion


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Z- or E-Configurate
✍ F. VON DER OHE; R. BRUECKNER πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 1 views

Alkylidenebutenolides from a 2-(Trimethylsiloxy)furan and Iodomethacrolein -Stereoselective Synthesis of Z-and E-Freelingyne. -Via an aldol/Ξ²-elimination approach as key sequence the title products such as (V) and (VI) are prepared. It is noteworthy that an earlier described method with triflic anh