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ChemInform Abstract: Stereoselective Synthesis of 1-Substituted (1E,3E)-1,3-Butadienyl Phenyl Tellurides and Internal Vinylic Tellurides.

✍ Scribed by J. W. SUNG; C. P. PARK; J. M. GIL; D. Y. OH

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 organo-tellurium compounds, isocyclic C derivatives organo-tellurium compounds, isocyclic C derivatives S 0144

42 -168

Stereoselective Synthesis of 1-Substituted (1E,3E)-1,3-Butadienyl Phenyl Tellurides and Internal Vinylic Tellurides.

-A general, one-pot and highly regio-and stereoselective method for the preparation of the title compounds (IV) and (VI) is developed. Key step is a selective migration of the alkenyl or alkyl group from boron to the adjacent alkynyl sp-carbon atom.

-(SUNG,

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