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ChemInform Abstract: Stereoselective Reductive Tetraallylation of Pyridinecarboxylic Acids by Triallylborane.

โœ Scribed by Yu. N. Bubnov; E. E. Demina; V. K. Bel'sky; G. V. Zatonsky; A. V. Ignatenko

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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Stereoselectivity in the Birch Reduction of 2-Furoic Acid Derivatives. -Birch reduction of the chiral amide (I) of 2-furoic acid and following electrophilic quench gives the dihydrofuroic amides (III) with high diastereoselectivity. Acidic cleavage of the chiral auxiliary liberates the carboxylic a