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ChemInform Abstract: Stereoselective Reaction of Arylsulfanyl-Stabilized Homoenolates with Aldehydes.

โœ Scribed by T. SHINOZUKA; Y. KIKORI; M. ASAOKA; H. TAKEI

Book ID
112031406
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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Intramolecular Reaction of (ฮณ-Alkoxyallyl)stannane with Aldehyde: Origin of the Stereoselectivities. -The Lewis acid-mediated cyclization of acyclic (ฮณ-alkoxyallyl)stannane aldehydes leads to trans-substituted cyclic ethers predominantly or exclusively, irrespective of the geometry of the double bon