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ChemInform Abstract: Stereoselective Oxymercuration of Cyclopropylcarbinols with Anchimeric Assistance by Aromatic Groups.

✍ Scribed by Janine Cossy; Nicolas Blanchard; Christophe Meyer

Book ID: 101927016
Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200227092

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Cyclopropylcarbinols bearing an adjacent stereocenter substituted by a phenyl group undergo anchimerically assisted mercurations, leading after reductive demercuration to oxygenated heterocycles or acyclic alcohols depending on the relative configurations.

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