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ChemInform Abstract: Stereoselective Intramolecular 1,3-Dipolar Cycloadditions

โœ Scribed by Irishi N. N. Namboothiri; Alfred Hassner


Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereochemistry. Pa
โœ I. N. N. NAMBOOTHIRI; A. HASSNER; H. E. GOTTLIEB ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB

Strategy for the Construction of Functionalized Five-and Six-Membered Carbocycles. -Conjugate addition of the Grignard reagents (II) and (IV) to the nitro olefins (I) leads to the intermediate formation of nitronates, which are trapped as silyl nitronates and subsequently cyclized by intramolecular