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ChemInform Abstract: Stereoselective Conversion of 2′,3′-Dideoxydidehydro Carbocyclic Nucleosides into 2′-Deoxy Carbocyclic Nucleosides.

✍ Scribed by J. V. BARKLEY; A. DHANDA; L. J. S. KNUTSEN; M.-B. NIELSEN; S. M. ROBERTS; D. R. VARLEY


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Stereoselective Conversion of 2',3'-Dideoxydidehydro Carbocyclic Nucleosides into 2'-Deoxy Carbocyclic Nucleosides.

-A novel transformation of known alkenes such as (I) to the 2'-deoxy derivatives such as (V) and (VI) is presented. It is noteworthy that the use of N-bromoacetamide instead of NBS as reagent is possible. The stereochemistry of compound (IVa) is confirmed by X-ray analysis. -(BARKLEY,


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