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ChemInform Abstract: Stereoselective Cascade Reactions for Construction of Polyfunctionalized Octahydroquinolines via [2C + 2C + 1C,1N] Cyclization.

✍ Scribed by Ankita Rai; Atul K. Singh; Pankaj Singh; Lal Dhar S. Yadav

Publisher: John Wiley and Sons
Year: 2011
Weight: 27 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201126158

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Stereoselective Synthesis of α-C-(Alkynyl)-glycosides via Ring-Opening of α-1,2-Anhydrosugars. -In the presence of ZnCl2 the α-1,2-epoxide function in sugars is selectively ring-opened by lithium alkynyl derivatives to form α -glycosides with retention of configuration. -