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ChemInform Abstract: Stereoselective and Diversity-Oriented Synthesis of Trisubstituted Allylic Alcohols and Amines.

✍ Scribed by Yvonne Schmidt; Bernhard Breit

Publisher
John Wiley and Sons
Year
2012
Weight
37 KB
Volume
43
Category
Article
ISSN
0931-7597

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Stereoselective and Diversity-Oriented S
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## Abstract Stereoselective and diversity‐oriented synthesis of trisubstituted olefins was achieved by using __ortho__‐diphenylphosphanyl benzoate (__o__‐DPPB) as a directing group for allylic substitution. The starting point of this methodology was a set of α‐methylene aldehydes derived from Bayli

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## Abstract α‐Stannylated allylic carbonates (I) smoothly undergo Pd‐catalyzed amination to give the corresponding stannylated allylic amines (III), which are suitable substrates for Pd‐catalyzed Stille coupling reactions [cf.