𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Stereoselective Alkylation of Sulfoxides and Sulfones Derived from (R)- Cysteine.

✍ Scribed by E. V. DEHMLOW; S. PIEPER; B. NEUMANN; H.-G. STAMMLER


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Stereoselective Alkylation of Sulfoxides
✍ Dehmlow, Eckehard Volker ;Pieper, Stefanie ;Neumann, Beate ;Stammler, Hans-Georg πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 664 KB

## Abstract (__R__)‐Cysteinol was protected as its oxazoline derivatives 1a–c and oxidized to the sulfoxides 2, 3 and the sulfone 7. These compounds could be alkylated under chelate control to give tertiary and quaternary stereogenic centers in a highly stereoselective manner to yield 4a–c,5, 8a–c,