Stereoselective Alkylation of Sulfoxides
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Dehmlow, Eckehard Volker ;Pieper, Stefanie ;Neumann, Beate ;Stammler, Hans-Georg
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Article
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1997
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John Wiley and Sons
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English
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## Abstract (__R__)βCysteinol was protected as its oxazoline derivatives 1aβc and oxidized to the sulfoxides 2, 3 and the sulfone 7. These compounds could be alkylated under chelate control to give tertiary and quaternary stereogenic centers in a highly stereoselective manner to yield 4aβc,5, 8aβc,