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ChemInform Abstract: Stereoselective Access to Substituted Enediyne Building Blocks.

✍ Scribed by George Hynd; Graham B. Jones; Gary W. Plourde II; Justin M. Wright

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Stereoselective Access to Substituted Enediyne Building Blocks. -Coupling/elimination of disubstituted propargyl bromides in the presence of LiN(Tms) 2 results in formation of tetrasubstituted olefins. The E:Z selectivity strongly depends on the nature of the propargylic substituent R. -(HYND,

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