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ChemInform Abstract: Stereoisomeric Imidazolo-Pentoses — Synthesis, Chiroptical Properties, and Evaluation as Glycosidase Inhibitors.

✍ Scribed by Theophile Tschamber; Herve Siendt; Arnaud Boiron; Francois Gessier; Dariusz Deredas; Andrzej Frankowski; Sylviane Picasso; Heinz Steiner; Anne-Marie Aubertin; Jacques Streith

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Stereomeric Pyrrolidinopentoses Bearing
Stereomeric Pyrrolidinopentoses Bearing an Imidazole Ring − Synthesis, Chiroptical Properties, and Evaluation as Potential Sugar-Mimic Glycosidase Inhibitors
✍ Théophile Tschamber; Hervé Siendt; Céline Tarnus; Dariusz Deredas; Andrzej Frank 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 487 KB

The syntheses of the imidazolo-pyrrolidino-pentoses ent-2 (Larabino), 3 (D-xylo), 4 (D-lyxo), ent-4 (L-lyxo), and 5 (D-ribo) are reported, completing the series of all eight possible stereomers. The corresponding five linear imidazolo sugar precursors were prepared by nucleophilic addition of C(4)me