ChemInform Abstract: Stereoelectronic Effects on π-Facial Selectivity in Addition to 4H-1,3-Dioxin-4-ones.
✍ Scribed by Fumiaki Uehara; Masayuki Sato; Chikara Kaneko
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Reaction of 2,2,6-Trimethyl-4H-1,3-dioxin-4-one with Imines: An Easy Route to Enamides. -Thermolysis of the dioxin (I) generates an acylketene which is readily trapped by imines to give the N-alkenyl acetoacetamides (III). They are useful intermediates in oxidative radical cyclizations leading to .