ChemInform Abstract: Stereodefined Ring Contraction—Rearrangement of Thiocoumarins to New Fused Benzo[b]thiophene Derivatives.
✍ Scribed by Massimiliano Cordaro; Giovanni Grassi; Antonio Rescifina; Ugo Chiacchio; Francesco Risitano; Angela Scala
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 50 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
Muenchnone (II) undergoes title ring contraction—rearrangement reaction with thiocoumarins having an electron‐withdrawing group at position 3 to give stereodefined fused polycyclic thienopyrroles.
📜 SIMILAR VOLUMES
A New Ring Contraction Rearrangement of 2,5-and 3,6-Di-tertbutyl-3H-azepines to Pyridine Derivatives. -A novel ring contraction reaction of di-tert-butyl-substituted 3H-azepines furnishing pyridine derivatives under bromination conditions is described. A plausible mechanism for the rearrangement via