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ChemInform Abstract: Stereocontrolled Synthesis of the BC Ring System of Taxol.

✍ Scribed by I. SHIINA; H. IWADARE; H. SAKOH; Y. TANI; M. HASEGAWA; K. SAITOH; T. MUKAIYAMA

Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
29
Category
Article
ISSN
0931-7597

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Synthesis of Both Enantiomers of the BC-Ring Part of Ciguatoxin. -The protected title enantiomers (XIV) and (XV) are synthesized starting with D-galactose and using the discrimination of the protecting groups benzyl and 4-methoxybenzyl of the common meso-like intermediate (XI) as the key step. -(OK