The cross-coupling reaction of trans-alkenylboronic acids with α-bromoacetic esters was firstly studied. It was found that using Pd(OAc) 2 as catalyst, a bulky electron-rich phospine, (2-dicyclohexylphospino-biphenyl) as ligand, the reaction can be readily accomplished to give specific (E)-β,γ-unsat
ChemInform Abstract: Stereocontrolled Synthesis of (E)-β,γ-Unsaturated Esters via Palladium-Catalyzed Cross-Coupling of (E)-Alkenylboronic Acids with α-Bromoacetic Esters.
✍ Scribed by Yazhen Duan; Jianshe Zhang; Jun Yang; Minzhi Deng
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 25 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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