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ChemInform Abstract: Stereocontrolled Mukaiyama-Type Aldol Reaction of Siloxypyrroles Derived from (S)-Glutamic Acid.

✍ Scribed by H. UNO; J. E. BALDWIN; I. CHURCHER; A. T. RUSSELL


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereochemical Chan
✍ H. UNO; N. MIZOBE; Y. YAMAOKA; N. ONO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB πŸ‘ 2 views

Stereochemical Change in the Lewis Acid-Promoted Reaction of 2-Siloxypyrrole Derived from (L)-Glutamic Acid. Synthesis of a Lactacystin Analogue. -The enantiopure pyrrolooxazole (I) react with aliphatic aldehydes [cf. (II)] stereoselectively to yield either the isomers (IV) or (VIII) as major produ