ChemInform Abstract: Stereocontrolled Intermolecular Radical Additions to Methylidenepiperazine-2,5-diones.
β Scribed by Christina L. L. Chai; Alison R. King
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Highly Diastereoselective Intermolecular Ξ²-Addition of Alkyl Radicals to Chiral 2-(Arylsulfinyl)-2-cycloalkenones. -The reaction of cycloalkenones having chiral bulky arylsulfinyl groups proceeds with excellent diastereoselectivity. In the presence of the Lewis acids EtAlCl 2 and TiCl 2 (OiPr) 2 re