ChemInform Abstract: Stereocontrol in the Nucleophilic Epoxidation of α-(1- Hydroxyalkyl)-α,β-Unsaturated Sulfones.
✍ Scribed by R. F. W. JACKSON; S. P. STANDEN; W. CLEGG; A. MCCAMLEY
- Book ID
- 112022371
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
THE epoxidation of a,B-unsatured carbonyl compounds by hydrogen peroxide in alkaline media is known to be non-stereospecific, yielding the same epoxide from either stereoisomaric 1.2 reactant. Alkaline epoxidation of a,B-unsatured sulfones show similar features, as it was reported that treatment of
Microwave-Promoted Epoxidation of α,β-Unsaturated Ketones in Aqueous Sodium Perborate -[as a safe, mild and convenient synthetic approach to α,β-epoxyketones].
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