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ChemInform Abstract: Stereocontrol in Organic Synthesis Using Silicon-Containing Compounds. A Synthesis of (-)-Tetrahydrolipstatin Using the Alkylation of a β-Silyl Ester and the Hydroboration of an Allylsilane.

✍ Scribed by I. FLEMING; N. J. LAWRENCE

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereocontrol in Organic Synthesis Using Silicon-Containing Compounds. A Formal Synthesis of (.+-.)-Thienamycin.
✍ I. FLEMING; J. D. KILBURN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

Stereocontrol in Organic Synthesis Using Silicon-Containing Compounds. A Formal Synthesis of (±)-Thienamycin. -The precursor (IX) of the title antibiotic is prepared from aldol product (Ib), which has a silyl group in the side chain as hydroxy surrogate. The trans disposed substituents at the azeti